Bleach: Shattered Blade (Wii)

New Characters
To unlock the new characters you'll need to kick butt. Enlightenment ensues:

• Shihouin Yoruichi
  Clear Training Mode

• Soi Fon
  Clear Episode Mode with Shihouin Yoruichi

• Tousen Kaname
  Clear Arcade Mode with Komamura Sajin

• Ukitake Juushiro
  Clear Arcade Mode with Kyouraku Shunsui

• Ulquiorra
  Clear Arcade Mode with Ichimaru Gin

• Urahara Kisuke
  Clear Arcade Mode with Kurotsuchi Mayuri

• Yamada Hanatarou
  Beat Story Mode with Youshiro Hitsugaya.

• Yamamoto Genryuusai Shigekuni
  Clear Arcade Mode with Ukitake Juushiro

• Yumichika Ayasegawa
  Clear Arcade Mode with Madarame Ikkaku

• Aizen Sousuke
  Clear Arcade Mode with Ulquiorra

• Arturo Plateado
  Clear Episode Mode with Arturo Plateado

• Grimmjow Jaggerjack
  Clear Arcade Mode with Aizen Sousuke

• Hinamori Momo
  Clear Hitsugaya Toushiro's story

• Hisagi Shuuhei
  Clear Episode Mode with Yamada Hanatarou

• Ichimaru Gin
  Clear Arcade Mode with Matsumoto Rangiku and Kira Izuru

• Kuchiki Rukia
  Beat Story mode with Abarai Renji

• Kurotsuchi Mayuri
  Clear Arcade Mode with Ishida Uryuu

• Kusajishi Yachiru
  Clear Arcade Mode with Yumichika Ayasegawa and Zaraki Kenpachi

• Kyouraku Shunsui
  Clear Arcade Mode with Sado Yasutora

• Madarame Ikkaku
  Clear Episode Mode with Zaraki Kenpachi

• Ikkaku School Costume  -  Win 10 matches with Madarame Ikkaku

• Masked Komamura Costume  -  Win 15 matches with Komamura Sajin

• Orihime School Costume  -  Win 15 matches with Inoue Orihime

• Renji School Costume  -  Win 15 matches with Abarai Renji

• Rukia School Costume  -  Win 15 matches with Kuchiki Rukia

• Shihouin Yoruichi Shunpo Costume  -  After completing practice mode, win 15 matches with Yoruichi

• Urahara Kisuke Shinigami Costume  -  Unlock everything, It becomes available for free in Urahara's Shop

• Yumichika School Costume  -  Win 10 matches with Ayasegawa Yumichika

• Hitsugaya School Costume  -  Win 15 matches with Toushiro Hitsugaya

• Matsumoto School Costume  -  AFTER unlocking Inoue Orihime's costume, win 15 matches with Matsumoto Rangiku

New Stages
To unlock the Arturo Battle Stage, you have to defeat Arturo Plateado on the final stage of episode mode.
Then to unlock the Ice Haven Stage, you must complete Hitsugaya's episode mode.